@Paige Hawthorne
ISO a reasonably believable explanation of how someone could doctor a 5.56 NATO round so it would explode β in the rifle barrel β when fired. But wouldn't end up killing, or even physically harming, the shooter.
If the shooter is firing an AR type (even a standard Ruger Mini-14) weapon, then ... not going to happen this way. These are gas operated weapons.
Firing sequence is follows. Trigger is pulled, operating the lower receiver. Hammer goes forward, hits the back of the firing pin, which then hits the back of the round, igniting the cap and thus the powder. These weapons fire closed bolt - so the bullet (the actual lead projectile) is shot forward, leaving the casing behind. The gases from the firing of the round travel down the barrel behind the bullet, and some of them go through a little tube just above the barrel itself, towards a matching receiving tube on top of the bolt.
That's what cycles the weapon back, opens the bolt, ejector shoots the casing out, (and at the same time pushing the hammer back down again as well) and as the bolt comes forward again, it strips another round out of the magazine, making it ready to fire.
Or, just watch this little video on YouTube:
https://www.youtube.com/watch?v=-sjGzvyQcvg
When you're talking about an explosion in the barrel, that's not what would happen if you plugged the end of the barrel - putting something in there to impede the bullet itself from coming out. Modern AR type weapons have strong enough barrels that they're not going to explode if the bullet stops. But that gas is going to have to go somewhere - which means you're going to see that shoving the bolt back on its own, and escaping that way.
Assume your shooter is standing and is right handed, so he's got his right cheek on the stock and taking aim. A properly (or improperly) held AR just really doesn't have squat for recoil. Oh, you put a couple hundred rounds downrange, you might feel it in your shoulder the next day. But that's about it.
https://www.youtube.com/watch?v=8T3qjpZB6ME
So ... bullet stuck in chamber, and presuming it's before the gas tube opening, means the shooter is going to feel a bigger jerk than normal, and suddenly the hot gas is going to shoot out the ejection port, and that's about it. There won't be an explosion, not like this:
https://www.youtube.com/watch?v=Fkz_Zuo8g0U
Note that the rifle that split in this last video is NOT going to be firing 5.56 rounds. That's a Remington 700, which is a bolt-action rifle that fires 7.62 or .30 caliber rounds. You COULD get a bolt-action (meaning single shot) rifle to explode by jamming something (NOT your finger) into the barrel.
Shotgun barrels are typically not made of the same steel as rifle barrels, and thus are easier to make go bang by plugging them. They just simply don't have to contain the pressures.
I never saw it, but I heard of a guy firing a live round down the barrel while his blank adapter was still attached. Didn't do much harm, other than get him in a crap load of trouble (and they scrapped the rifle).
As for doctoring the round itself ... not really. The video with the Remington splitting says the guy put the wrong powder in. So it generated TOO much pressure, making the barrel split because it has to wait for the bullet to exit the barrel before the gases escape. You put 'hot' powder into a 5.56 round, it's going to simply shove the bolt back quicker, still sending the bullet downrange.